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Environmental Stress Cracking

Environmental stress cracking (ESC) is a well known but not always understood phenomenon with plastics. ESC occurs in plastic-lined parts when the plastic liner is exposed to chemical liquid while under mechanical or thermal stress. ESC can lead to failures at stresses below the tensile strength of the material. In some instance, the presence of a contaminant may act as an accelerator. For example, iron or copper contamination in concentrated sulfuric or hydrochloric acid can result in stress cracking of polypropylene liners. All plastics, including PTFE, are known to be susceptible to ESC.

The occurrence of ESC is hard to predict. It is dependent on the process chemistry, operating conditions, physical piping system layout and quality of field fabrication of the piping system. In the chemical resistance tables, certain chemical/liner ratings are linked to this document. This indicates the liner is contact with that specific chemical may be susceptible to ESC. This does not mean the liner in question will not work, but additionally data must be gathered to ensure that the liner is compatible with the chemical. If the chemical in question is suspected of causing ESC with a particular plastic liner and testing cannot be done to determine suitability, choose an alternative liner from the chemical resistance tables.


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