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Anhydrous Hydrogen Bromide
Anhydrous hydrogen bromide is an irritating, colorless, corrosive gas
at standard temperature and pressure. The gas fumes strongly in moist
air. Commercial anhydrous hydrogen bromide is available in cylinders
as a compressed liquefied gas. Cylinders should be kept away from
heat and sunlight during storage.
The cylinder delivery tube should never be inserted in a liquid or
gas without a vacuum break, check valve or other protective apparatus
in the line because suck-back into the cylinder may product an
explosion. Anhydrous HBr can be handled with piping materials having
adequate corrosion resistance for hydrochloric acid service. Brittle
materials should be avoided if the chance of impact damage exists.
Anhydrous HBr is used in the preparation of organic bromides and as
a catalyst in the controlled oxidation of organic materials and the
alkylation and cracking of petroleum products. |
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Typical Properties of Anhydrous Hydrogen Bromide |
| Specific gravity of liquid |
2.77 (-67°C) (-89°F) |
| Density of gas |
3.5 gm/liter (0°C, 1 atm.) (32°F) |
| Boiling point |
-67°C (1 atm.) (-89°F) |
| Melting point |
-87°C (-125°F) |
| Solubility |
Soluble in water and methanol
at 25°C (77°F) |
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