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Chlorine Dioxide

Typical properties of ClO2 anhydrous
Density 1.642 g/cc (0°C)
Boiling Point 10°C
Freezing Point -56.5°C
Heat of Vaporization 6520 g-cal/mol (for liquid ClO2)

 
Vapor pressure of chlorine dioxide

T (K°)
p (mm Hg)
206 7
214 (mp) 10
223 24
232.5 47
243.5 88
255 201
273 490
278.3 608
279.9 642
281 674
282 700
283 732
284 (bp) 760

 
Solubility of ClO2 in water

t, °C
gms ClO2 per Liter
Solid Phase
-0.79 Eutec. 26.98 ClO2·8H2O + Ice
0 27.59 ClO2·8H2 O ± 1H2O
1 29.48 "
5.7 42.10 "
10 60.05 "
15.3 87.04 "
10.7 tr. pt. 107.9 " + liquid ClO2
14 more than 107.9 liquid ClO2
10.7 116.7 "
1 more than 108.6 "
The exact composition of the hydrate could not be determined due to manipulative difficulties


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